5-Bromo-4-iodo-2-methylaniline
نویسندگان
چکیده
The asymmetric unit of the title compound, C(7)H(7)BrIN, contains two independent mol-ecules, which are linked by weak N-H⋯N hydro-den-bonding inter-actions between the amino groups.
منابع مشابه
(E)-N-[(6-Bromopyridin-2-yl)methylidene]-4-methylaniline
The title compound, C(13)H(11)BrN(2), a Schiff base obtained from 6-bromo-picolinaldehyde and p-toluidine, has an E configuration about the C=N bond. The dihedral angle between the benzene and pyridine rings is 30.4 (1)°.
متن کامل3-Amino-5-bromo-2-iodopyridine
The reaction of 3-amino-5-bromo-pyridine with N-iodo-succinimide in the presence of acetic acid produces the title compound, C(5)H(4)BrIN, with an iodo substituent in position 2 of the pyridine ring. The crystal structure features rather weak inter-molecular N-H⋯N hydrogen bonds linking the mol-ecules into chains along the z axis of the crystal.
متن کامل3,4,5-triarylisothiazoles via C-C coupling chemistry.
The regiocontrolled preparation of triarylisothiazoles is presented. 3-Halo-5-phenylisothiazole-4-carbonitriles, 1 (hal=Cl) and 18 (hal=I), are converted into the corresponding 4-bromo derivatives 5 (3-hal=Cl) and 24 (3-hal=I) via a Hunsdiecker strategy while the 4-iodo analogues 7 (3-hal=Cl) and 22 (3-hal=I) are prepared via a Hoffmann and Sandmeyer strategy. Regioselective Suzuki, Stille and ...
متن کامل(E)-4-Bromo-N-{(E)-3-[(4-bromo-2-methylphenyl)imino]butan-2-ylidene}-2-methylaniline
The title compound, C(18)H(18)Br(2)N(2), is centrosymmetric with the mid-point of the central C-C bond of the butyl group located on an inversion center. The terminal benzene ring is approximately perpendicular to the central butyl plane [dihedral angle = 71.9 (8)°]. No hydrogen bonding or aromatic stacking is observed in the crystal.
متن کامل4-Iodo-2-methylaniline
In the mol-ecule of the title compound, C(7)H(8)IN, the methyl C, I and N atoms lie in the benzene ring plane. In the crystal structure, inter-molecular N-H⋯N hydrogen bonds link the mol-ecules in a stacked arrangement along the a axis.
متن کامل